The pathway with the name Phosmet
 has the following structure: 
Result: 
COP(=O)(OC)SCN1C(=O)C2=C(C=CC=C2)C1=O
 no rule associatedC1=CC2=C(C=C1)C(=O)N(CS)C2=O
C1=CC(=C(C=C1)C(=O)O)C(=O)N
 no rule associatedC1=CC(=C(C=C1)C(=O)O)C(=O)O
COP(=S)(OC)SCN1C(=O)C2=C(C=CC=C2)C1=O
 no rule associatedC1=CC2=C(C=C1)C(=O)N(CS)C2=O
C1=CC2=C(C=C1)C(=O)NC2=O
 no rule associatedC1=CC(=C(C=C1)C(=O)O)C(=O)N
C1=CC2=C(C=C1)C(=O)N(CO)C2=O
 no rule associatedC1=CC2=C(C=C1)C(=O)NC2=O
COP(=O)(OC)SCN1C(=O)C2=C(C=CC=C2)C1=O
 no rule associatedC1=CC2=C(C=C1)C(=O)N(CO)C2=O
C1=CC2=C(C=C1)C(=O)N(CS(=O)O)C2=O
 no rule associatedC1=CC(=C(C=C1)C(=O)O)C(=O)NCS(=O)(=O)O
C1=CC2=C(C=C1)C(=O)N(CS)C2=O
 no rule associatedC1=CC2=C(C=C1)C(=O)N(CS(=O)O)C2=O
COCNC(=O)C1=C(C=CC=C1)C(=O)O
 no rule associatedCOCN1C(=O)C2=C(C=CC=C2)C1=O
COCN1C(=O)C2=C(C=CC=C2)C1=O
 no rule associatedCOCNC(=O)C1=C(C=CC=C1)C(=O)O
COP(=S)(OC)SCN1C(=O)C2=C(C=CC=C2)C1=O
 no rule associatedCOCN1C(=O)C2=C(C=CC=C2)C1=O
CS(=O)CN1C(=O)C2=C(C=CC=C2)C1=O
 no rule associatedCS(=O)(=O)CN1C(=O)C2=C(C=CC=C2)C1=O
CS(=O)(=O)CN1C(=O)C2=C(C=CC=C2)C1=O
 no rule associatedCS(=O)(=O)CNC(=O)C1=C(C=CC=C1)C(=O)O
COP(=S)(OC)SCN1C(=O)C2=C(C=CC=C2)C1=O
 no rule associatedCOP(=O)(OC)SCN1C(=O)C2=C(C=CC=C2)C1=O
C1=CC2=C(C=C1)C(=O)N(CO)C2=O
 no rule associatedC1=CC(=C(C=C1)C(=O)O)C(=O)NCO
CSCNC(=O)C1=C(C=CC=C1)C(=O)O
 no rule associatedCS(=O)CNC(=O)C1=C(C=CC=C1)C(=O)O
CSCN1C(=O)C2=C(C=CC=C2)C1=O
 no rule associatedCS(=O)CN1C(=O)C2=C(C=CC=C2)C1=O
COP(=S)(OC)SCN1C(=O)C2=C(C=CC=C2)C1=O
 no rule associatedCOP(=S)(OC)S
COP(=S)(OC)SCN1C(=O)C2=C(C=CC=C2)C1=O
 no rule associatedCOP(O)OC
CSCN1C(=O)C2=C(C=CC=C2)C1=O
 no rule associatedCSCNC(=O)C1=C(C=CC=C1)C(=O)O
CS(=O)CN1C(=O)C2=C(C=CC=C2)C1=O
 no rule associatedCS(=O)CNC(=O)C1=C(C=CC=C1)C(=O)O
CS(=O)CNC(=O)C1=C(C=CC=C1)C(=O)O
 no rule associatedCS(=O)(=O)CNC(=O)C1=C(C=CC=C1)C(=O)O
C1=CC2=C(C=C1)C(=O)N(CS)C2=O
 no rule associatedCSCN1C(=O)C2=C(C=CC=C2)C1=O

Description: Phosmet degraded rapidly in soil under aerobic and anaerobic conditions to a large variety of products. Phosmet undergoes the basic reactions typical for dialkyl aryl dithiophosphate triesters. This includes desulfuration to form the oxon and cleavage of the “anhydride bond” (at either the carbon-sulfur bond or the sulfur-phosphorus bond) to split the molecule into dialkyl phosphate moiety and an aryl moiety with or without a sulfhydryl group depending on the point of cleavage. The aryl moiety is further degraded through a variety of reactions, including sulfhydryl group oxidation to sulfonic acid, sulfhydryl group methylation followed by sulfoxidation, and imide bond cleavage. Ultimately, mineralisation to carbon dioxide occurs. The metabolite N-Hydroxymethyl phthalamic acid occurred with an amount >10 % of applied radioactivity and therefore, N-Hydroxymethyl phthalamic acid has to be considered as major metabolite. None metabolite was found above 10% under aerobic conditions.
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