The pathway with the name Malathion
 has the following structure: 
Result: 
CCOC(=O)CCC(=O)[O-]
 no rule associatedC(CC(=O)[O-])C(=O)[O-]
[O-]P(=S)([O-])[O-]
 no rule associatedO=P([O-])([O-])[O-]
COP(=S)([O-])OC
 no rule associatedCOP(=O)([O-])OC
CCOC(=O)CC(C(=O)OCC)SP(=S)(OC)OC
 no rule associatedCO
CCOC(=O)CC(C(=O)OCC)SP(=S)([O-])OC
CCOC(=O)CC(C(=O)OCC)SP(=S)(OC)OC
 no rule associatedCCO
CCOC(=O)C(CC(=O)[O-])SP(=S)(OC)OC
COP(=O)([O-])[O-]
 no rule associatedCO
O=P([O-])([O-])[O-]
CCOC(=O)CC(C(=O)OCC)SP(=O)([O-])OC
 no rule associatedCO
CCOC(=O)CC(C(=O)OCC)SP(=O)([O-])[O-]
CCOC(=O)CC(C(=O)OCC)SP(=O)([O-])[O-]
 no rule associatedO=P([O-])([O-])[O-]
CCOC(=O)CC(C(=O)OCC)S
COP(=S)(OC)S
 no rule associatedCOP(=S)([O-])OC
CCOC(=O)CC(C(=O)OCC)SP(=O)(OC)OC
 no rule associatedCCOC(=O)CC(C(=O)OCC)SP(=O)([O-])OC
CO
CCOC(=O)CC(C(=O)OCC)SP(=S)(OC)OC
 no rule associatedCCOC(=O)CC(C(=O)OCC)O
COP(=O)([O-])OC
 no rule associatedCO
COP(=O)([O-])[O-]
COP(=S)([O-])OC
 no rule associatedCO
COP(=S)([O-])[O-]
CCOC(=O)CC(C(=O)OCC)S
 no rule associatedCCOC(=O)CCC(=O)OCC
CCOC(=O)CC(C(=O)OCC)SP(=S)(OC)OC
 no rule associatedCCOC(=O)CC(C(=O)OCC)SP(=O)(OC)OC
CCOC(=O)CCC(=O)OCC
 no rule associatedCCOC(=O)CCC(=O)[O-]
COP(=S)(OC)SC(CC(=O)[O-])C(=O)[O-]
 no rule associatedC(C(=O)C(=O)[O-])C(=O)[O-]
COP(=S)(OC)S
CCOC(=O)C(CC(=O)[O-])SP(=S)(OC)OC
 no rule associatedCCO
COP(=S)(OC)SC(CC(=O)[O-])C(=O)[O-]
COP(=S)([O-])[O-]
 no rule associatedCO
[O-]P(=S)([O-])[O-]

Description: Malathion is an organophosphate pesticide commonly used in the United States for controlling mosquito populations. The toxicity of malathion is low but acute exposure in high doses may cause a variety of symptoms including nausea, dizziness, or confusion. Malaoxon is a potent cholinesterase inhibitor that can be formed from malathion under certain conditions. Exposure to malaoxon can lead to complications in the central nervous system (Edwards, 2006. US Environmental Protection Agency - Prevention, Pesticides and Toxic Substances EPA 738-R-06-030). The predominant biodegradation pathway for malathion involves formation of mono- and diacid metabolites through carboxylesterase activity. Oxidative desulfurization and demethylation leads to complete mineralization. Other minor routes of metabolism include initial oxidation to remove sulfur and methyl groups ([http://www.ncbi.nlm.nih.gov/pubmed/402103|Laveglia and Dahm, 1977]). Pseudomonas aeruginosa AA112 is able to use malathion as a sole carbon source. [http://www.ncbi.nlm.nih.gov/pubmed/17896475|Abo-Amer (2007)] observed the formation of diethylsuccinate and succinate metabolites. The intermediate steps in this pathway have not been characterized. However, the reduction of -SH to -H (diethyl 2-mercaptosuccinate -> diethylsuccinate) may be abiotic ([http://www.ncbi.nlm.nih.gov/pubmed/12713326|Hebting et al., 2003]).
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