The pathway with the name Benzoate
 has the following structure: 
Result: 
C1=CC2=C(C=C1)S(=O)(=O)NC2=O
 no rule associatedC1=CC(=C(C=C1)O)O
C1=CC=C(C=C1)C(=O)[O-]
 no rule associatedC1=C[C@@H]([C@](C=C1)(C(=O)[O-])O)O
CC(C)(COP(=O)(O)OP(=O)(O)OCC1C(C(C(N2C=NC3=C2N=CN=C3N)O1)O)OP(=O)(O)O)C(C(=O)NCCC(=O)NCCSC(=O)C4=CC=CC=C4)O
 no rule associatedCC(C)(COP(=O)([O-])OP(=O)([O-])OCC1C(C(C(N2C=NC3=C2N=CN=C3N)O1)O)OP(=O)([O-])[O-])C(C(=O)NCCC(=O)NCCSC(=O)C4=CC=CC5C4O5)O
CC(C)(COP(=O)([O-])OP(=O)([O-])OCC1C(C(C(N2C=NC3=C2N=CN=C3N)O1)O)OP(=O)([O-])[O-])C(C(=O)NCCC(=O)NCCSC(=O)C/C=C\CC(=O)[O-])O
 no rule associatedCC(C)(COP(=O)(O)OP(=O)(O)OCC1C(C(C(N2C=NC3=C2N=CN=C3N)O1)O)OP(=O)(O)O)C(C(=O)NCCC(=O)NCCSC(=O)CCC(=O)[O-])O
CC(=O)SCCNC(=O)CCNC(=O)C(C(C)(C)COP(=O)(O)OP(=O)(O)OCC1C(C(C(N2C=NC3=C2N=CN=C3N)O1)O)OP(=O)(O)O)O
CC(C)(COP(=O)([O-])OP(=O)([O-])OCC1C(C(C(N2C=NC3=C2N=CN=C3N)O1)O)OP(=O)([O-])[O-])C(C(=O)NCCC(=O)NCCSC(=O)C4=CC=CC5C4O5)O
 no rule associatedCC(C)(COP(=O)([O-])OP(=O)([O-])OCC1C(C(C(N2C=NC3=C2N=CN=C3N)O1)O)OP(=O)([O-])[O-])C(C(=O)NCCC(=O)NCCSC(=O)C/C=C\CC=O)O
C1=CC(=C(C=C1)Cl)C(=O)[O-]
 no rule associatedC1=CC(=C(C=C1)O)O
C1=CC=C(C=C1)C(=O)[O-]
 no rule associatedC1=C(C=CC(=C1)O)C(=O)[O-]
CC(C)(COP(=O)([O-])OP(=O)([O-])OCC1C(C(C(N2C=NC3=C2N=CN=C3N)O1)O)OP(=O)([O-])[O-])C(C(=O)NCCC(=O)NCCSC(=O)C/C=C\CC=O)O
 no rule associatedCC(C)(COP(=O)([O-])OP(=O)([O-])OCC1C(C(C(N2C=NC3=C2N=CN=C3N)O1)O)OP(=O)([O-])[O-])C(C(=O)NCCC(=O)NCCSC(=O)C/C=C\CC(=O)[O-])O
C1=C[C@@H]([C@](C=C1)(C(=O)[O-])O)O
 no rule associatedC1=CC(=C(C=C1)O)O
C1=CC=C(C=C1)C(=O)[O-]
 no rule associatedCC(C)(COP(=O)(O)OP(=O)(O)OCC1C(C(C(N2C=NC3=C2N=CN=C3N)O1)O)OP(=O)(O)O)C(C(=O)NCCC(=O)NCCSC(=O)C4=CC=CC=C4)O

Description: Benzoate is a colorless or light yellow transparent liquid with very faint floral odor. It is an excellent solvent of synthetic musks and vanillin, and a fixative in bouguet perfumes. Benzoate is a common intermediate in the anaerobic metabolism of aromatic compounds, documented elsewhere in the UMBBD. Two branches for aerobic benzoate metabolism are dioxygenation to form catechol, found in some bacteria ([http://www.ncbi.nlm.nih.gov/pubmed/1938949|Harayama et al., 1991]), and monooxygenation to form protocatechuate, used mostly by fungi ([http://www.ncbi.nlm.nih.gov/pubmed/4026866|Sahasrabudhe et al., 1985]). Azoarcus evansii and some other bacteria use a third branch, starting with ligation with CoA to form benzoyl-CoA, and its monooxygenation to form the 2,3-epoxy compound. This is followed by hydrolysis of the epoxide, possibly with transient oxepin formation, to form 2,4-dehydroadipyl-CoA semialdehyde, and oxidation of this to 3,4-dehydroadipyl-CoA. This last compound is metabolized to succinyl-CoA and acetyl-CoA in several uncharacterized steps. This branch occurs in 4.5% of 649 bacteria whose genomes have been sequenced, compared to the 7% that contain the dioxygenase branch ([http://www.ncbi.nlm.nih.gov/pubmed/20452977|Rather et al., 2010]). 2-Chlorobenzoate and saccharin biodegradation is also included on this pathway map. 2-Chlorobenzene is used as a preservative for glues and paints and an intermediate in the manufacture of fungicides, dyes, pharmaceuticals and other organic chemicals. Saccharin, o-Benzosulfimide, is used as a flavoring agent and non-nutritive sweetener.
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