The pathway with the name Haloxyfop-P (DE-535)
 has the following structure: 
Result: 
CC(C(=O)O)OC1=CC=C(C=C1)OC2=NC=C(C=C2Cl)C(F)(F)F
 no rule associatedC1=C(C(=NC=C1C(F)(F)F)O)Cl
C1=C(C=CC(=C1)OC2=NC=C(C=C2Cl)C(F)(F)F)O
 no rule associatedC1=C(C(=NC=C1C(F)(F)F)O)Cl
CC(C(=O)O)OC1=CC=C(C=C1)OC2=NC=C(C=C2Cl)C(F)(F)F
 SequentialCompositeRule(uri = https://envipath.org/package/6e470eef-b954-41a1-8c61-8ccdf9a8544a/sequential-rule/65cabf47-b1cc-4688-8e75-3ecec004c84b) CN1C=C(C=C(C1=O)Cl)C(F)(F)F
C1=C(C=CC(=C1)OC2=NC=C(C=C2Cl)C(F)(F)F)O
 no rule associatedC(=O)=O
CC(C(=O)OC)OC1=CC=C(C=C1)OC2=NC=C(C=C2Cl)C(F)(F)F
 no rule associatedC1=C(C=CC(=C1)OC2=NC=C(C=C2Cl)C(F)(F)F)O
C1=C(C=CC(=C1)OC2=NC=C(C=C2Cl)C(F)(F)F)O
 SequentialCompositeRule(uri = https://envipath.org/package/6e470eef-b954-41a1-8c61-8ccdf9a8544a/sequential-rule/65cabf47-b1cc-4688-8e75-3ecec004c84b) CN1C=C(C=C(C1=O)Cl)C(F)(F)F
CN1C=C(C=C(C1=O)Cl)C(F)(F)F
 no rule associatedC(=O)=O
CC(C(=O)OC)OC1=CC=C(C=C1)OC2=NC=C(C=C2Cl)C(F)(F)F
 SimpleRule(uri = https://envipath.org/package/32de3cf4-e3e6-4168-956e-32fa5ddb0ce1/simple-rule/57d978b5-f55f-462e-a9dc-c5908d165973, SMIRKS = [#6:2]-[#8:1]-[#6:6](-[#1,#6:3])=[O:7]>>[H][#8]-[#6:2].[#8-:1]-[#6:6](-[#1,#6:3])=[O:7]) CC(C(=O)O)OC1=CC=C(C=C1)OC2=NC=C(C=C2Cl)C(F)(F)F
C1=C(C(=NC=C1C(F)(F)F)O)Cl
 no rule associatedC(=O)=O
CC(C(=O)O)OC1=CC=C(C=C1)OC2=NC=C(C=C2Cl)C(F)(F)F
 SimpleRule(uri = https://envipath.org/package/32de3cf4-e3e6-4168-956e-32fa5ddb0ce1/simple-rule/cf2bc731-6b0c-4f1d-b192-8e859d9505aa, SMIRKS = [H][#6;A;!$([#6]=[#8]):3]!@-[#8:2]!@-[#6;!$([#6]=[#8]):1]>>[#6:1]-[#8:2].[#6;A:3]=O) C1=C(C=CC(=C1)OC2=NC=C(C=C2Cl)C(F)(F)F)O

Description: Results from two studies (Knowles (2001) and Hale & Trigg (1994)) suggested a possible degradation route for DE-535 under aerobic conditions. DE-535 degraded rapidly to produce DE-535 acid, which was further degraded to DE-535 phenol, DE-535 pyridinol and DE-535 pyridinone. A direct degradation of DE-535 to form DE-535 phenol is also suggested, but no suggestions as to when this route is preferred are indicated. The mineralisation at 20°C accounted for 32% AR with 14C-phenyl labelling and 6.3% AR with 14C-pyridinol labelling after 90 days (one soil). WIth 14C-pyridinol labelling four soils showed a mineralisation of 1.0 - 3.3% AR after 92 days and one soil 6.2% AR after 90 days. Non-extractable residues at 20°C accounted for 44% AR after 90 days with 14C-phenyl labelling and 38% AR with 14C-pyridinol labelling (one soil). Four other soils with 14C-pyridinol labelling had NER values in the range 28 - 35% AR, while one soil differs with only 3.4% AR. The metabolites DE-535 acid, DE-535 phenol, DE-535 pyridinol and DE-535 pyridinone were monitored in the study by Knowles (2001), whereas the study by Hale & Trigg (1994) did not monitor for DE-535 pyridinone. Nevertheless, in the study by Hale & Trigg (1994) an unknown metabolite, referred to as U2, was possible identical to DE-535 pyridinone. The main degradation products were Haloxyfop-R and DE-535 pyridinol. The soil metabolism studies covering six soils under standard conditions showed that Haloxyfop-R far exceeded the trigger value of 10% AR in all six soils with max concentrations ranging from 53 to 91% AR. DE-535 pyridinol too exceeded the trigger value in all the six soils with maximum concentrations from 29 to 52% AR. Therefore, DE-535 acid and DE-535 pyridinol are major metabolites and should be further investigated in field studies. 
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