The pathway with the name Sulcotrione
 has the following structure: 
Result: 
CS(=O)(=O)C1=CC=C(C(=C1)Cl)C(=O)C2C(=O)CCCC2=O
 no rule associatedC(CC(=O)O)CC(=O)O
CS(=O)(=O)C1=CC=C(C(=C1)Cl)C(=O)C2C(=O)CCCC2=O
 SimpleRule(uri = https://envipath.org/package/32de3cf4-e3e6-4168-956e-32fa5ddb0ce1/simple-rule/9bdcc525-2cb5-4d14-bf00-193dd44b9585, SMIRKS = [#6:6]-[#6:2](=[O:7])-[#6;X4:1]-[#6:5]([#6,#16;A:4])=[O:8]>>[#6:1]-[#6:5]([#6,#16;A:4])=[O:8].[#6:6]-[#6:2](-[#8-])=[O:7]) CS(=O)(=O)C1=CC=C(C(=C1)Cl)C(=O)O
C(CC(=O)O)CC(=O)O
 no rule associatedC(CC(=O)O)C(=O)O
CS(=O)(=O)C1=CC=C(C(=C1)Cl)C(=O)O
 no rule associatedC(=O)=O
C(CC(=O)O)C(=O)O
 no rule associatedC(=O)=O

Description: The degradation route of sulcotrione was investigated using a silt loam with application rates of 1 and 100 ppm, respectively, and at a temperature of 5°C (for 1 ppm only) and 25°C. Several substances assumed as potential metabolites were used as references, namely: ICIA0051-4-OH, ICIA0051-5-OH, ICIA0051-xanothene, ICIA0051-MBA and ICIA0051-CMBA. Apart from CMBA none of the other references was detected in the course of the study. However, two minor unknown metabolites occurred after 92 days at concentrations each below 1% of the applied radioactive material. The main metabolite CMBA showed its climax 30 days after incubation with a concentration of 28.7% (1 ppm, 25°C). At the subsequent sampling days at study end (day 60, 92 and 120) CMBA concentration finally decline to 11%. At the end of the study, the parent compound was present at a concentration of 5.5% TAR. Mineralisation of sulcotrione was found to be extensive with > 50% CO2 after 120 days. The formation of bound residues increased to a plateau around 25% TAR (day 60- end of the study). Obviously, the degradation of sulcotrione proceeds via one main route, i.e. through the cleavage of the cyclohexane moiety and the formation of 2-chloro-4-methylsulfonyl benzoic acid (CMBA) which is further mineralised. The conversion to CO2 presumably is by the classic ring cleavage mechanism mediated by hydroxylations followed by the formation of catechol. Suspected cleavage products of the dione are succinic acid and glutaric acid. When formed, these acids are expected to be rapidly incorporated into biomass through the tricarboxylic acid cycle. 
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