The pathway with the name Benzyl Sulfide
 has the following structure: 
Result: 
C1=CC=C(C=C1)CSCC2=CC=CC=C2
 SimpleRule(uri = https://envipath.org/package/32de3cf4-e3e6-4168-956e-32fa5ddb0ce1/simple-rule/fe9bb9f7-f1ef-4f9e-8eaa-0f7b84c2ff6b, SMIRKS = [#6:2][#16;D2;!$([#16+]([C])[C]):1][#6,#7:3]>>[#6:2][S:1]([#6,#7:3])=O) C1=CC=C(C=C1)CS(=O)CC2=CC=CC=C2
C1=CC=C(C=C1)CSSCC2=CC=CC=C2
 SimpleRule(uri = https://envipath.org/package/32de3cf4-e3e6-4168-956e-32fa5ddb0ce1/simple-rule/d14503d1-9b95-47cb-a634-3339f781456f, SMIRKS = [#6:3]-[#16:2]-[#16:1]-[#6:4]>>[#6:4]-[#16:1]([H]).[#6:3]-[#16:2]([H])) C1=CC=C(C=C1)CS
C1=CC=C(C=C1)CS
 no rule associatedC1=CC=C(C=C1)CSSCC2=CC=CC=C2
C1=CC=C(C=C1)CS(=O)CC2=CC=CC=C2
 SimpleRule(uri = https://envipath.org/package/32de3cf4-e3e6-4168-956e-32fa5ddb0ce1/simple-rule/50dcd2bd-c7f9-4767-a049-bccb04d0c84c, SMIRKS = [#6,#8:3]-,:[#16;A;!$([#16+]([C])[C]):1](-,:[#6,#8:2])=[O:5]>>[#6,#8:3][S:1]([#6,#8:2])(=O)=[O:5]) C1=CC=C(C=C1)CS(=O)(=O)CC2=CC=CC=C2
C1=CC=C(C=C1)CS(=O)CC2=CC=CC=C2
 SimpleRule(uri = https://envipath.org/package/32de3cf4-e3e6-4168-956e-32fa5ddb0ce1/simple-rule/50dcd2bd-c7f9-4767-a049-bccb04d0c84c, SMIRKS = [#6,#8:3]-,:[#16;A;!$([#16+]([C])[C]):1](-,:[#6,#8:2])=[O:5]>>[#6,#8:3][S:1]([#6,#8:2])(=O)=[O:5]) C1=CC=C(C=C1)CS(=O)(=O)CC2=CC=CC=C2
C1=CC=C(C=C1)CSCC2=CC=CC=C2
 SimpleRule(uri = https://envipath.org/package/32de3cf4-e3e6-4168-956e-32fa5ddb0ce1/simple-rule/fe9bb9f7-f1ef-4f9e-8eaa-0f7b84c2ff6b, SMIRKS = [#6:2][#16;D2;!$([#16+]([C])[C]):1][#6,#7:3]>>[#6:2][S:1]([#6,#7:3])=O) C1=CC=C(C=C1)CS(=O)CC2=CC=CC=C2
C1=CC=C(C=C1)CSCC2=CC=CC=C2
 SimpleRule(uri = https://envipath.org/package/32de3cf4-e3e6-4168-956e-32fa5ddb0ce1/simple-rule/e41d9d65-6adf-417b-a36d-dcd56aa160a8, SMIRKS = [H][#6:3](-[#1,#6:7])-[#16;v2:1]-[#1,#6,#15:2]>>[#1,#6:7]-[#6:3]=O.[H][#16;v2:1]-[#1,#6,#15:2]) C1=CC=C(C=C1)CS
C1=CC=C(C=C1)C=O

Description: Benzyl sulfide contains a thioether bond of the type found in bis(2-chloroethyl) sulfide. Bis(2-chloroethyl) sulfide, also known as Yperite or mustard gas, is the most produced and stored chemical weapon. It is highly cytotoxic and is a carcinogenic and mutagenic alkylating agent; benzyl sulfide has been used as a non-toxic model for its metabolism. The microbial degradation of benzyl sulfide can be carried out by white-rot (Coriolous versicolor) and brown-rot (Tyromyces palustris) fungi ([http://www.ncbi.nlm.nih.gov/pubmed/9256235|Itoh et al., 1997]). The initial step may be the oxidative cleavage of the C-S bond to yield benzaldehyde and benzyl mercaptan. Benzaldyde can be reduced to benzyl alcohol or oxidized to benzoate. Benzyl mercaptan can be converted to benzyl disulfide in the presense or absence of fungi. Degradation of the disulfide to the mercaptan was observed in the presence of fungi. Benzaldehyde, benzyl alcohol, and benzoate follow the toluene pathway and are finally mineralized to CO2 and H2O. These and several other fungi can also oxide benzyl sulfide to the sulfoxide and the sulfone ([http://www.ncbi.nlm.nih.gov/pubmed/12571066|Van Hamme et al., 2003]), and this may be the primary aerobic route. The first oxidation step is catalyzed by extracellular enzymes such as laccase, but the second step is cytochrome P450 (unspecific monooxygenase) mediated. Rhodococcus sp. strain IGTS8 can perform these same two oxidations using a single sulfide/sulfoxide monooxygenase ([http://www.ncbi.nlm.nih.gov/pubmed/8824615|Lei and Tu, 1996]).
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